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Beilstein J. Org. Chem. 2013, 9, 2137–2146, doi:10.3762/bjoc.9.251
Graphical Abstract
Scheme 1: Reaction intermediates, resulting products, and model cations.
Scheme 2: Sn(IV)-catalyzed isomerization of nitronic esters.
Scheme 3: Thermal rearrangement of nitronic esters 2 and 3.
Scheme 4: Thermal rearrangement of nitronic esters 21a, 21b and 22b.
Scheme 5: Thermal reactions of nitronic esters 5, 7, and 26a–d.
Scheme 6: General transition state for the [3,3]-sigmatropic rearrangement of O-allyl nitronic esters.
Scheme 7: Thermal rearrangement of nitronic ester 30.